Is it not possible to clone a repository using Git on PyCharm?

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No, it is possible to clone a repository using Git on PyCharm. To do so, navigate to the VCS menu and select "Checkout from Version Control" and select "Git". This will open a dialog box where you can enter the URL of the repository you want to clone and specify the location where you want to save it. Once you click "Clone", PyCharm will download the repository and open it as a project.